Structure and Physical Properties of SrNiRu\u3csub\u3e5\u3c/sub\u3eO\u3csub\u3e11\u3c/sub\u3e Single Crystals: An \u3cem\u3eR\u3c/em\u3e-Type Ferrite Based on Ordered Kagome Nets

Single crystals of the R-type ferrite SrNiRu5O11 were grown from a chloride flux. The hexagonal crystal structure contains ruthenium located on distorted kagome nets. The low-temperature dc magnetic susceptibilities (χ⊥ and χ∥, perpendicular and parallel to the c axis, respectively) diverge as T−0.3, and do not exhibit any indication of long-range magnetic order down to 4.5 K. The electrical resistivity varies as T1.6 below 40 K, which is typical of non-Fermi liquids, and may originate from a competition between residual magnetic interactions among Ni2+ (S = 1) spins and geometrical frustration on the two-dimensional kagome lattice of Ru3+ (S = ½) spins. The transverse magnetoresistivity ρxy at constant temperature T = 5 K for current (J) -magnetic field (H) configurations, J⊥H ∥ c axis and J ∥ H⊥c axis, reveals no anomalous contribution, which is consistent with the absence of magnetic order. Fits of the specific heat data below 10 K require a dominant, but unusual electronic term of the form Cel = γT1.2, which is expected for massless Dirac fermion states in topological insulators, or spin-liquid phases

Coexistence of Ferromagnetism and Unconventional Spin-Glass Freezing in the Site-Disordered Kagome Ferrite SrSn\u3csub\u3e2\u3c/sub\u3eFe\u3csub\u3e4\u3c/sub\u3eO\u3csub\u3e11\u3c/sub\u3e

Single-crystal x-ray diffraction refinements indicate SrSn2Fe4O11 crystallizes in the hexagonal R-type ferrite structure with noncentrosymmetric space group P63mc and lattice parameters a = 5.9541(2)Å, c = 13.5761(5)Å, Z = 2 (R(F) = 0.034). Octahedrally coordinated 2a [M(1) and M(1a)] and 6c sites [M(2)] have random, mixed occupation by Sn and Fe; whereas the tetrahedrally coordinated 2b sites [Fe(3) and Fe(3a)] are exclusively occupied by Fe, whose displacement from the ideal position with trigonal-bipyramidal coordination causes the loss of inversion symmetry. Our dc and ac magnetization data indicate SrSn2Fe4O11 single crystals undergo a ferro- or ferri-magnetic transition below a temperature TC = 630 K with very low coercive fields μoHc⊥ = 0.27 Oe and μoHc∥ = 1.5 Oe at 300 K, for applied field perpendicular and parallel to the c axis, respectively. The value for TC is exceptionally high, and the coercive fields exceptionally low, among the known R-type ferrites. Time-dependent dc magnetization and frequency-dependent ac magnetization data indicate the onset of short-range, spin-glass freezing below Tf = 35.8 K, which results from crystallographic disorder of magnetic Fe3+ and nonmagnetic Sn4+ ions on a frustrated Kagome sublattice. Anomalous ac susceptibility and thermomagnetic relaxation behavior in the short-range-ordered state differs from that of conventional spin glasses. Optical measurements in the ultraviolet to visible frequency range in a diffuse reflectance geometry indicate an overall optical band gap of 0.8 eV, consistent with observed semiconducting properties

Class of Ferromagnetic Semiconductors

Single crystal and polycrystal oxoruthenates having the generalized compositions (Baz,Sr1−z)FexCoyRu6−(x+y)O11 (1≦(x+y)≦5; 0≦z≦1) and (Ba,Sr)M2±xRu4∓xO11 (M=Fe,Co) belong to a novel class of ferromagnetic semiconductors with applications in spin-based field effect transistors, spin-based light emitting diodes, and magnetic random access memories

Strongly Localized Magnetization Modes in Permalloy Antidot Lattices

Antidot lattices (ADLs) patterned into soft magnetic thin films exhibit rich ferromagnetic resonance (FMR) spectra corresponding to many different magnetization modes. One of the predicted modes is highly localized at the edges of the antidots; this mode is difficult to detect experimentally. Here we present FMR data for a permalloy thin film patterned into a square array of square antidots. Comparison of these data with micromagnetic simulations permits identification of several edge modes. Our simulations also reveal the effect of the antidot shape on the mode dispersion

Electrical Control of Structural and Physical Properties via Strong Spin-Orbit Interactions in Sr\u3csub\u3e2\u3c/sub\u3eIrO\u3csub\u3e4\u3c/sub\u3e

Electrical control of structural and physical properties is a long-sought, but elusive goal of contemporary science and technology. We demonstrate that a combination of strong spin-orbit interactions (SOI) and a canted antiferromagnetic Mott state is sufficient to attain that goal. The antiferromagnetic insulator Sr2IrO4 provides a model system in which strong SOI lock canted Ir magnetic moments to IrO6 octahedra, causing them to rigidly rotate together. A novel coupling between an applied electrical current and the canting angle reduces the Néel temperature and drives a large, nonlinear lattice expansion that closely tracks the magnetization, increases the electron mobility, and precipitates a unique resistive switching effect. Our observations open new avenues for understanding fundamental physics driven by strong SOI in condensed matter, and provide a new paradigm for functional materials and devices

Direct Imaging of Coexisting Ordered and Frustrated Sublattices in Artificial Ferromagnetic Quasicrystals

We have used scanning electron microscopy with polarization analysis and photoemission electron microscopy to image the two-dimensional magnetization of permalloy films patterned into Penrose P2 tilings (P2T). The interplay of exchange interactions in asymmetrically coordinated vertices and short-range dipole interactions among connected film segments stabilize magnetically ordered, spatially distinct sublattices that coexist with frustrated sublattices at room temperature. Numerical simulations that include long-range dipole interactions between sublattices agree with images of as-grown P2T samples and predict a magnetically ordered ground state for a two-dimensional quasicrystal lattice of classical Ising spins

Ferromagnetic resonance study of eightfold artificial ferromagnetic quasicrystals

We have performed broadband (10 MHz–18 GHz) and narrowband (9.7 GHz) ferromagnetic resonance (FMR) measurements on permalloy thin films patterned with quasiperiodic Ammann tilings having eightfold rotational symmetry. We observed highly reproducible mode structures in the low-frequency, hysteretic regime in which domain walls and unsaturated magnetization textures exist. A minimum of 10 robust modes were observed in patterned samples, compared to the single uniform mode observed in unpatterned permalloy films. The field dependence and approximate eightfold rotational symmetry of the FMR spectra are in good agreement with micromagnetic simulations that confirm the importance of patterning for controlling static and dynamic magnetic response

Novel Magnetism of Ir\u3csup\u3e5+\u3c/sup\u3e(5\u3cem\u3ed\u3c/em\u3e\u3csup\u3e4\u3c/sup\u3e) Ions in the Double Perovskite Sr\u3csub\u3e2\u3c/sub\u3eYIrO\u3csub\u3e6\u3c/sub\u3e

We synthesize and study single crystals of a new double-perovskite Sr2YIrO6. Despite two strongly unfavorable conditions for magnetic order, namely, pentavalent Ir5+(5d4) ions which are anticipated to have Jeff=0 singlet ground states in the strong spin-orbit coupling (SOC) limit and geometric frustration in a face-centered cubic structure formed by the Ir5+ ions, we observe this iridate to undergo a novel magnetic transition at temperatures below 1.3 K. We provide compelling experimental and theoretical evidence that the origin of magnetism is in an unusual interplay between strong noncubic crystal fields, local exchange interactions, and “intermediate-strength” SOC. Sr2YIrO6 provides a rare example of the failed dominance of SOC in the iridates

Evidence for a Low-Temperature Magnetic Ground State in Double-Perovskite Iridates with Ir\u3csup\u3e5+\u3c/sup\u3e(5\u3cem\u3ed\u3c/em\u3e\u3csup\u3e4\u3c/sup\u3e) Ions

We report an unusual magnetic ground state in single-crystal, double-perovskite Ba2YIrO6 and Sr-doped Ba2YIrO6 with Ir5+(5d4) ions. Long-range magnetic order below 1.7 K is confirmed by dc magnetization, ac magnetic susceptibility, and heat-capacity measurements. The observed magnetic order is extraordinarily delicate and cannot be explained in terms of either a low-spin S = 1 state, or a singlet Jeff = 0 state imposed by the spin-orbit interactions (SOI). Alternatively, the magnetic ground state appears consistent with a SOI that competes with comparable Hund\u27s rule coupling and inherently large electron hopping, which cannot stabilize the singlet Jeff = 0 ground state. However, this picture is controversial, and conflicting magnetic behavior for these materials is reported in both experimental and theoretical studies, which highlights the intricate interplay of interactions that determine the ground state of materials with strong SOI